全文获取类型
收费全文 | 85288篇 |
免费 | 10629篇 |
国内免费 | 7355篇 |
专业分类
电工技术 | 8145篇 |
技术理论 | 20篇 |
综合类 | 2885篇 |
化学工业 | 11755篇 |
金属工艺 | 6756篇 |
机械仪表 | 2507篇 |
建筑科学 | 5843篇 |
矿业工程 | 3827篇 |
能源动力 | 5910篇 |
轻工业 | 5157篇 |
水利工程 | 3742篇 |
石油天然气 | 12339篇 |
武器工业 | 1044篇 |
无线电 | 7459篇 |
一般工业技术 | 8449篇 |
冶金工业 | 6271篇 |
原子能技术 | 1152篇 |
自动化技术 | 10011篇 |
出版年
2024年 | 212篇 |
2023年 | 3026篇 |
2022年 | 4244篇 |
2021年 | 4807篇 |
2020年 | 5383篇 |
2019年 | 4218篇 |
2018年 | 3475篇 |
2017年 | 4339篇 |
2016年 | 4759篇 |
2015年 | 4628篇 |
2014年 | 6420篇 |
2013年 | 7343篇 |
2012年 | 9083篇 |
2011年 | 7860篇 |
2010年 | 5529篇 |
2009年 | 5438篇 |
2008年 | 2985篇 |
2007年 | 4362篇 |
2006年 | 4052篇 |
2005年 | 2080篇 |
2004年 | 1107篇 |
2003年 | 1049篇 |
2002年 | 1048篇 |
2001年 | 1007篇 |
2000年 | 857篇 |
1999年 | 909篇 |
1998年 | 588篇 |
1997年 | 451篇 |
1996年 | 511篇 |
1995年 | 248篇 |
1994年 | 201篇 |
1993年 | 125篇 |
1992年 | 158篇 |
1991年 | 94篇 |
1990年 | 84篇 |
1989年 | 74篇 |
1988年 | 54篇 |
1987年 | 73篇 |
1986年 | 74篇 |
1985年 | 32篇 |
1984年 | 48篇 |
1983年 | 41篇 |
1982年 | 43篇 |
1981年 | 32篇 |
1980年 | 49篇 |
1979年 | 7篇 |
1978年 | 4篇 |
1976年 | 8篇 |
1959年 | 34篇 |
1951年 | 16篇 |
排序方式: 共有10000条查询结果,搜索用时 265 毫秒
1.
《International Journal of Hydrogen Energy》2022,47(90):38114-38123
High-temperature water electrolysis through solid oxide electrolysis cells (SOEC) will play a key role in building a hydrogen economy in the future. However, the delamination between the air electrode and the electrolyte remains a critical issue to be addressed. Previously, it was hypothesized that Co migration may improve the catalytic activity of the SrZrO3 second phase at the LSCF-YSZ interface, eventually leading to the delamination. In this work, the LSCF-YSZ interfaces sintered at different temperatures were examined in detail. The activation behaviors of the LSCF electrodes upon application with electrolysis current were characterized under different conditions. Further, samples containing purposely added SrZrO3 interlayer with and without cobalt were fabricated and compared. The activation process is less significant for the sample with cobalt-added SrZrO3 interlayer than the sample with pure SrZrO3 layer, supporting the hypothesis that Co migration may lead to the activation behavior. 相似文献
2.
通过固液掺杂、等静压压制、中频烧结的方法,制备了不同的氧化镧、氧化钇、氧化锆三元掺杂成分比例的钨电极材料烧结棒材,探究了不同成分配比对样品显微组织、第二相粒子分布以及宏观力学性能的影响。结果表明,氧化镧、氧化钇、氧化锆三元复合添加能够有效改善第二相粒子在钨基体中的分布形态,降低第二相在晶界的过度富集,提高钨电极材料的综合力学性能。并且当添加成分镧、钇、锆质量比为3:1:1时,材料具有最好的综合力学性能,致密度可达96.04%,显微硬度可达549.37HV0.3,抗压强度可达3785MPa,原因是此配比下第二相粒子最为细小均匀,弥散程度最高,对基体晶粒的细化作用最好,该配比下钨基体平均晶粒尺寸达到10.3μm。 相似文献
3.
4.
Diffusers are widely-used to quickly dilute effluents in receiving water bodies. This study proposed a novel diffuser that pre-mixes effluent with ambient water before discharging and that uses the swirling jet to further enhance near-field dilution. The nozzle of the diffuser was examined in two ambient flow conditions: co-flow and counter-flow that are commonly-met in the environment such as oceans due to tidal effect. Physical experiments were first conducted in co-flow on its dilution performance and hydrodynamics, using heated water as the effluent. A 3-D CFD model was developed and calibrated the co-flow scenarios, and then used to investigate the diffuser in counter-flow. The results showed that the nozzle can effectively reduce the maximum temperature rise of the effluent by about 50 % before discharging. The swirling jet from the outlet has a larger shear area, half-width and entrainment rate, enabling the effluent to be rapidly diluted to a minimum of around 10 times at x/D = 6 in co-flow, whereas the dilution for conventional nozzles is about 1 because of the potential core. The flow amplification ratio (α) decreases gradually with increasing velocity ratio in co-flow but increases with increasing velocity ratio in counter-flow. The counter-flow reduces the water drawn into the device; however, the pre-dilution effect at the outlet remains stable. The near-field dilution in counter-flow was significantly enhanced than that in co-flow. Environmental regulations at outfalls and mixing zones can be more easily met using this novel diffuser. 相似文献
5.
我国的矿业权出让制度改革正在全面推进,合理评价区块期望价值对于油公司的区块进退决策至关重要。对于含有多个勘探目标的成熟探区,简单地将各目标价值相加通常会高估区块期望价值,应综合考虑两方面的因素:一是各勘探目标的地质情况,包括相对空间位置关系、地质成功率、资源规模和地质相关性等;二是油公司的勘探策略,包括干井承受能力、承诺钻井数量、对各目标的钻探次序等。为此,从油公司区块进退决策实际出发,提出一套基于概率论的勘探目标群期望价值估算方法,并通过实例讨论了上述因素对区块期望价值的影响。 相似文献
6.
摘 要:核心网业务模型的建立是5G网络容量规划和网络建设的基础,通过现有方法得到的理论业务模型是静态不可变的且与实际网络存在偏离。为了克服现有5G核心网业务模型与现网模型适配性较差以及规划设备无法满足用户实际业务需求的问题,提出了一种长短期记忆(long short-term memory,LSTM)网络与卷积LSTM (convolution LSTM,ConvLSTM)网络双通道融合的 5G 核心网业务模型预测方法。该方法基于人工智能(artificial intelligence,AI)技术以实现高质量的核心网业务模型的智能预测,形成数据反馈闭环,实现网络自优化调整,助力网络智能化建设。 相似文献
7.
针对芳香硝基化合物的催化选择性加氢反应,开发可替代贵金属催化剂的低成本、高效非贵金属催化剂,对于芳香胺类化合物的绿色生产具有重要意义。利用简易、可规模化的制备方法,以镍—2,5-吡啶二羧酸金属有机框架为前驱体,热解制备了氮掺杂石墨碳包覆镍纳米催化材料(Ni@CN)。采用X射线衍射、扫描电镜、透射电镜、元素分析、N2吸脱附等检测手段对Ni@CN的物化性质进行了表征,并对其催化性能进行了评价。结果表明,Ni@CN可在温和条件下(85℃,1.0 MPa H2)高效加氢含取代官能团的芳香硝基化合物生成对应的芳香胺类化合物。对比试验表明,镍纳米颗粒是Ni@CN的加氢活性中心,而石墨碳壳的存在有利于优先吸附硝基官能团。此外,进一步考察了Ni@CN的循环使用性能以及抗硫化物中毒的特性。 相似文献
8.
《Ceramics International》2022,48(12):16808-16812
Flash sintering has been reported in various ceramics. Nevertheless, anion and cation conductors exhibit different flash-sintering behaviors, and the interaction mechanism between the conductive species and the sintering environment has remained unclear. Herein, we report the flash-sintering phenomena of a typical cation conductor, Na3Zr2(SiO4)2(PO4) with anode region surrounded by air and NaNO3 environments. The results prove that the ionic behavior and joule heating distribution can be controlled by changing the electrode environment. Four possible scenarios describing the ion migration behavior and interaction with the environment are proposed for providing a guidance for controlling the ion interaction behavior during flash sintering. 相似文献
9.
《International Journal of Hydrogen Energy》2022,47(12):7836-7845
Catalyst samples for CH4 decomposition were prepared from red mud (RM) by an acid-leaching neutralization precipitation approach. Water-washing the resultant precipitates multiple times, followed by drying at 105 °C and calcination at 500 °C, resulted in a threshold of residual Na2O, equivalent to 96% Na2O removal. Drying the precipitate at a higher temperature of 200 °C, followed by repeated water washing, provided a deeper Na2O removal of 99% and made the resultant samples more active for the targeted reaction. Subsequently, four catalyst samples with a simulated red mud composition and NaOH contents from 0 to 0.3 wt% were prepared and the catalytic test results revealed that the Na2O remaining in the RM-derived catalysts did not only inhibit their activation in CH4 but also lower their maximal activities for CH4 decomposition. Finally, two catalysts with the same simulated red mud composition and their Na impregnated respectively on Fe2O3 and a mixture support of Al2O3-SiO2-TiO2 were prepared and tested to explore the effect of Na distribution on the activation behavior of RM-derived catalysts for CH4 decomposition. The activity testing results showed that it was the Na residual dispersed on iron oxides in the RM-derived samples to significantly inhibit the activation of CH4 decomposition. 相似文献
10.
基于电信运营商数字化转型,系统性地提出了数据驱动的云网发展规划体系,以及六大关键数字化能力构建,设计和实现了一种云网规划数字化平台,该平台可用于实现目标网络精细规划、边缘计算精准预测等场景,并探讨了数字孪生在规划领域的应用前景,对运营商推进云网融合战略、推进高质量发展具有指导和参考意义。 相似文献